Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.
نویسندگان
چکیده
Silyl, phosphinyl, stannyl, and boryl reagents can be added across the neutral metal-carbon dative bond in d(0) f-block metal N-heterocyclic carbene complexes in a reversible manner, allowing additional functional groups to be incorporated into redox-inactive organo-f-block compounds.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 12 شماره
صفحات -
تاریخ انتشار 2010